The symmetric group is -transitive and the alternating group is -transitive. It is known that any other group can be at most 5-transitive. The Mathieu group is 5-transitive:
There is just one orbit, and hence it is transitive:
The stabilizer of 1 acts transitively on the remaining 23 points, and hence is 2-transitive:
It is also 3-transitive, 4-transitive, and 5-transitive:
But it is not 6-transitive because there are two nontrivial orbits now: