Unicode: 2242. Alias: Esc =~ Esc. Infix similarity operator. x ≂ y is by default interpreted as EqualTilde[x,y].
Unicode: 29E6 Alias: Esc equiv Esc. Infix operator with built-in evaluation rules. x ⧦ y is by default interpreted as Equivalent[x,y]. Not the same as \[DoubleLeftRightArrow] ...
Unicode: 22DB. Infix ordering operator. x ⋛ y is by default interpreted as GreaterEqualLess[x,y].
Unicode: 2267. Infix ordering operator. x ≧ y is by default interpreted as GreaterFullEqual[x,y].
Unicode: 226B. Infix ordering operator. x ≫ y is by default interpreted as GreaterGreater[x,y]. Not the same as \[RightGuillemet].
Unicode: 2277. Infix ordering operator. x ≷ y is by default interpreted as GreaterLess[x,y].
Unicode: 2A7E. Alias: Esc >/ Esc. Infix operator with built-in evaluation rules. x ⩾ y is by default interpreted as GreaterEqual[x,y].
Unicode: 2273. Alias: Esc >~ Esc. Infix ordering operator. x ≳ y is by default interpreted as GreaterTilde[x,y].
Unicode: 224E. Infix similarity operator. x ≎ y is by default interpreted as HumpDownHump[x,y]. Used to indicate geometrical equivalence.
Unicode: 21E4. Infix arrow operator. x ⇤ y is by default interpreted as LeftArrowBar[x,y]. Sometimes used to indicate a backtab. Extensible character.