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Upgrading from:

PieCharts`

As of Version 7, the Pie Charts Package has been integrated into the Wolfram System.

PieChart is now a built-in Mathematica function:

Version 6.0 << PieCharts`; PieChart[{.2, .3, .1, .5}]
Wolfram Language code: PieChart[{.2, .3, .1, .5}, ChartLabels -> Range[4], ChartStyle -> 1, SectorOrigin -> 0]

Specify radial spacing:

Version 6.0 << PieCharts`; PieChart[{.2, .3, .1, .5}, PieExploded -> All]
Wolfram Language code: PieChart[{.2, .3, .1, .5}, SectorSpacing -> {.1, Automatic}]